1-D arrays of porous MnCoO nanoneedles with an enhanced electrocatalytic activity toward the oxygen evolution reaction

Developing effective electrocatalysts for the oxygen evolution reaction (OER) that are highly efficient, abundantly available, inexpensive, and environmentally friendly is critical to improving the overall efficiency of water splitting and the large-scale development of water splitting technologies. We, herein, introduce a facile synthetic strategy for depositing the self-supported arrays of 1D-porous nanoneedles of a manganese cobalt oxide (Mn 0.21 Co 2.79 O 4 : MCO) thin film demonstrating an enhanced electrocatalytic activity for OER in an alkaline electrolyte. For this, an MCO film was synthesized via thermal treatment of a hydroxycarbonate film obtained from a hydrothermal route. The deposited films were characterized through scanning electron microscopy (SEM), X-ray diffractometry (XRD), energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). In contrast to a similar 1D-array of a pristine Co 3 O 4 (CO) nanoneedle film, the MCO film exhibits a remarkably enhanced electrocatalytic performance in the OER with an 85 mV lower overpotential for the benchmark current density of 10 mA cm 2 . In addition, the MCO film also demonstrates long-term electrochemical stability for the OER in 1.0 M KOH aqueous electrolyte. After substituting some Co 3+ ions with Mn 3+ ions in the Co 3 O 4 spinel crystal lattice, the resulting Mn 0.21 Co 2.79 O 4 nanoneedles demonstrate enhanced electrocatalysis in alkaline water oxidation.