A water stable and highly fluorescent Zn() based metal-organic framework for fast detection of Hg, Cr, and antibiotics

The development of luminescent metal-organic frameworks for effective sensing and monitoring of environmental pollutants is of great significance for human health and environmental protection. In this work, a novel water-stable Zn II -based luminescent coordination polymer, namely {[Zn(BBDF)(ATP)]·2DMF·3H 2 O} n ((BBDF = 2,7-bis(1 H -benzimidazol-1-yl)-9,9-dimethyl-9 H -fluorene) and H 2 ATP = 2-aminoterephthalic acid), was designed and obtained using the mixed-ligand method. Structural analysis indicated that 1 presents a two-fold interpenetrated two-dimensional layer structure with one dimensional (1D) channels along the a axis. Intriguingly, the uncoordinated -NH 2 group was danged onto the pore walls of 1 . Remarkably, compound 1 shows good aqueous stability at different pH values of 3-13 and exhibits a fluorescence turn-off sensing behavior for Hg 2+ , Cr 2 O 7 2− , CrO 4 2− , and antibiotics (NFZ, NFT) in aqueous solution with high selectivity and sensitivity. The limits of detection (LOD) are 0.12 μM (Hg 2+ ), 0.17 μM (Cr 2 O 7 2− ), 0.21 μM (CrO 4 2− ), 0.098 μM (NFZ), and 0.14 μM (NFT). The luminescence quenching mechanism analysis by experiment and theoretical calculation revealed that the competitive absorption and the photoinduced electron transfer process are largely responsible for the sensing of the two antibiotics, while the weak interaction contributes to the selective luminescence quenching for Hg 2+ . A water-stable two-fold interpenetrated LMOF ( 1 ) with 1D channel structure and uncoordinated −NH 2 group located onto the pore walls was obtained. 1 exhibits a fluorescent turn-off sensing behavior for Hg 2+ , Cr 2 O 7 2 − , CrO 4 2 − and antibiotics in aqueous solution.