Polymorphism in AMF (A = Rb, Cs; M = Al, Ga) grown using mixed halide fluxes
Single crystals of A 3 MF 6 (A = Rb, Cs; M = Al, Ga) were grown from mixed alkali chloride/fluoride fluxes in sealed silver tubes. For Cs 3 AlF 6 and Cs 3 GaF 6 , two polymorphs were observed at room temperature: m -Cs 3 MF 6 and o -Cs 3 MF 6 . For the two Rb containing compositions, only one room t...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2023-06, Vol.52 (24), p.8425-8433 |
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| container_end_page | 8433 |
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| container_issue | 24 |
| container_start_page | 8425 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 52 |
| creator | Morrison, Gregory Masachchi, Lakshani W Tisdale, Hunter B Chang, Tieyan Jones, Virginia G Zamorano, K. Pilar Breton, Logan S Smith, Mark D Chen, Yu-Sheng zur Loye, Hans-Conrad |
| description | Single crystals of A
3
MF
6
(A = Rb, Cs; M = Al, Ga) were grown from mixed alkali chloride/fluoride fluxes in sealed silver tubes. For Cs
3
AlF
6
and Cs
3
GaF
6
, two polymorphs were observed at room temperature:
m
-Cs
3
MF
6
and
o
-Cs
3
MF
6
. For the two Rb containing compositions, only one room temperature polymorph was observed:
o
-Rb
3
AlF
6
and
t
-Rb
3
GaF
6
, respectively. Simultaneous TGA/DSC and high temperature SCXRD/PXRD were used to study the high temperature behavior of A
3
MF
6
. The compounds of all four compositions were found to undergo structure transitions upon heating to the same cubic structure type,
c
-A
3
MF
6
.
Single crystals of A
3
MF
6
(A = Rb, Cs; M = Al, Ga) were grown from mixed alkali chloride/fluoride fluxes. The polymorphism of each compound was studied
via
TGA/DSC and high temperature X-ray diffraction. |
| doi_str_mv | 10.1039/d3dt00352c |
| format | Article |
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3
MF
6
(A = Rb, Cs; M = Al, Ga) were grown from mixed alkali chloride/fluoride fluxes in sealed silver tubes. For Cs
3
AlF
6
and Cs
3
GaF
6
, two polymorphs were observed at room temperature:
m
-Cs
3
MF
6
and
o
-Cs
3
MF
6
. For the two Rb containing compositions, only one room temperature polymorph was observed:
o
-Rb
3
AlF
6
and
t
-Rb
3
GaF
6
, respectively. Simultaneous TGA/DSC and high temperature SCXRD/PXRD were used to study the high temperature behavior of A
3
MF
6
. The compounds of all four compositions were found to undergo structure transitions upon heating to the same cubic structure type,
c
-A
3
MF
6
.
Single crystals of A
3
MF
6
(A = Rb, Cs; M = Al, Ga) were grown from mixed alkali chloride/fluoride fluxes. The polymorphism of each compound was studied
via
TGA/DSC and high temperature X-ray diffraction.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d3dt00352c</identifier><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2023-06, Vol.52 (24), p.8425-8433</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27902,27903</link.rule.ids></links><search><creatorcontrib>Morrison, Gregory</creatorcontrib><creatorcontrib>Masachchi, Lakshani W</creatorcontrib><creatorcontrib>Tisdale, Hunter B</creatorcontrib><creatorcontrib>Chang, Tieyan</creatorcontrib><creatorcontrib>Jones, Virginia G</creatorcontrib><creatorcontrib>Zamorano, K. Pilar</creatorcontrib><creatorcontrib>Breton, Logan S</creatorcontrib><creatorcontrib>Smith, Mark D</creatorcontrib><creatorcontrib>Chen, Yu-Sheng</creatorcontrib><creatorcontrib>zur Loye, Hans-Conrad</creatorcontrib><title>Polymorphism in AMF (A = Rb, Cs; M = Al, Ga) grown using mixed halide fluxes</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>Single crystals of A
3
MF
6
(A = Rb, Cs; M = Al, Ga) were grown from mixed alkali chloride/fluoride fluxes in sealed silver tubes. For Cs
3
AlF
6
and Cs
3
GaF
6
, two polymorphs were observed at room temperature:
m
-Cs
3
MF
6
and
o
-Cs
3
MF
6
. For the two Rb containing compositions, only one room temperature polymorph was observed:
o
-Rb
3
AlF
6
and
t
-Rb
3
GaF
6
, respectively. Simultaneous TGA/DSC and high temperature SCXRD/PXRD were used to study the high temperature behavior of A
3
MF
6
. The compounds of all four compositions were found to undergo structure transitions upon heating to the same cubic structure type,
c
-A
3
MF
6
.
Single crystals of A
3
MF
6
(A = Rb, Cs; M = Al, Ga) were grown from mixed alkali chloride/fluoride fluxes. The polymorphism of each compound was studied
via
TGA/DSC and high temperature X-ray diffraction.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjr0LgkAcQI8oyD6W9uA3Fmidd5pINIhkDQkR7WJ-Xpwf3CXpf19D1Nj0HrzlITTT8UrH1F7HNH5gTE0S9ZCiG5al2YQa_a-TzRCNpLxjTAg2iYJO54p3RSXqnMkCWAmO78HCgR1cbiq4cgv-2x2uwiFcQiaqZwmNZGUGBWuTGPKQsziBlDdtIidokIZcJtMPx2ju7a_uURMyCmrBilB0wW-R_usvG6Q7sw</recordid><startdate>20230620</startdate><enddate>20230620</enddate><creator>Morrison, Gregory</creator><creator>Masachchi, Lakshani W</creator><creator>Tisdale, Hunter B</creator><creator>Chang, Tieyan</creator><creator>Jones, Virginia G</creator><creator>Zamorano, K. Pilar</creator><creator>Breton, Logan S</creator><creator>Smith, Mark D</creator><creator>Chen, Yu-Sheng</creator><creator>zur Loye, Hans-Conrad</creator><scope/></search><sort><creationdate>20230620</creationdate><title>Polymorphism in AMF (A = Rb, Cs; M = Al, Ga) grown using mixed halide fluxes</title><author>Morrison, Gregory ; Masachchi, Lakshani W ; Tisdale, Hunter B ; Chang, Tieyan ; Jones, Virginia G ; Zamorano, K. Pilar ; Breton, Logan S ; Smith, Mark D ; Chen, Yu-Sheng ; zur Loye, Hans-Conrad</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d3dt00352c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2023</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Morrison, Gregory</creatorcontrib><creatorcontrib>Masachchi, Lakshani W</creatorcontrib><creatorcontrib>Tisdale, Hunter B</creatorcontrib><creatorcontrib>Chang, Tieyan</creatorcontrib><creatorcontrib>Jones, Virginia G</creatorcontrib><creatorcontrib>Zamorano, K. Pilar</creatorcontrib><creatorcontrib>Breton, Logan S</creatorcontrib><creatorcontrib>Smith, Mark D</creatorcontrib><creatorcontrib>Chen, Yu-Sheng</creatorcontrib><creatorcontrib>zur Loye, Hans-Conrad</creatorcontrib><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Morrison, Gregory</au><au>Masachchi, Lakshani W</au><au>Tisdale, Hunter B</au><au>Chang, Tieyan</au><au>Jones, Virginia G</au><au>Zamorano, K. Pilar</au><au>Breton, Logan S</au><au>Smith, Mark D</au><au>Chen, Yu-Sheng</au><au>zur Loye, Hans-Conrad</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymorphism in AMF (A = Rb, Cs; M = Al, Ga) grown using mixed halide fluxes</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2023-06-20</date><risdate>2023</risdate><volume>52</volume><issue>24</issue><spage>8425</spage><epage>8433</epage><pages>8425-8433</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Single crystals of A
3
MF
6
(A = Rb, Cs; M = Al, Ga) were grown from mixed alkali chloride/fluoride fluxes in sealed silver tubes. For Cs
3
AlF
6
and Cs
3
GaF
6
, two polymorphs were observed at room temperature:
m
-Cs
3
MF
6
and
o
-Cs
3
MF
6
. For the two Rb containing compositions, only one room temperature polymorph was observed:
o
-Rb
3
AlF
6
and
t
-Rb
3
GaF
6
, respectively. Simultaneous TGA/DSC and high temperature SCXRD/PXRD were used to study the high temperature behavior of A
3
MF
6
. The compounds of all four compositions were found to undergo structure transitions upon heating to the same cubic structure type,
c
-A
3
MF
6
.
Single crystals of A
3
MF
6
(A = Rb, Cs; M = Al, Ga) were grown from mixed alkali chloride/fluoride fluxes. The polymorphism of each compound was studied
via
TGA/DSC and high temperature X-ray diffraction.</abstract><doi>10.1039/d3dt00352c</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2023-06, Vol.52 (24), p.8425-8433 |
| issn | 1477-9226 1477-9234 |
| language | |
| recordid | cdi_rsc_primary_d3dt00352c |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Polymorphism in AMF (A = Rb, Cs; M = Al, Ga) grown using mixed halide fluxes |
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