Synthetic progress of organic thermally activated delayed fluorescence emitters C-H activation and functionalization

Thermally activated delayed fluorescence (TADF) emitters have become increasingly prominent due to their promising applications across various fields, prompting a continuous demand for developing reliable synthetic methods to access them. This review aims to highlight the progress made in the last decade in synthesizing organic TADF compounds through C−H bond activation and functionalization. The review begins with a brief introduction to the basic features and design principles of TADF emitters. It then provides an overview of the advantages and concise development of C−H bond transformations in constructing TADF emitters. Subsequently, it summarizes both transition-metal-catalyzed and non-transition-metal-promoted C−H bond transformations used for the synthesis of TADF emitters. Finally, the review gives an outlook on further challenges and potential directions in this field. This review highlights progress made in the last decade in the synthesis of thermally activated delayed fluorescence emitters through C-H bond transformations, and gives an outlook on further challenges and potential directions in this field.