Synthesis of SiN/SiS-heterocycles the reactions of a bis-silylene with isocyanate/isothiocyanate molecules

Reactions of o -carborane-fused bis-silylene 1 with isocyanate/isothiocyanate molecules furnished a series of SiN/SiS-heterocycles, which show distinct styles of cyclization and were theoretically studied. Reactions of o -carborane-fused bis-silylene with isocyanate/isothiocyanate molecules furnishe...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-01, Vol.6 (9), p.1148-1151
Hauptverfasser: Liu, Rui, Mondal, Kartik Chandra, Wang, Chenfeng, Suthar, Sonam, Fang, Zijie, Zuo, Darui, Li, Yan
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Zusammenfassung:Reactions of o -carborane-fused bis-silylene 1 with isocyanate/isothiocyanate molecules furnished a series of SiN/SiS-heterocycles, which show distinct styles of cyclization and were theoretically studied. Reactions of o -carborane-fused bis-silylene with isocyanate/isothiocyanate molecules furnished SiN/SiS-heterocycles via distinct cyclizations.
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc04950g