Trace Sc-electrolyte additive enabling stable Zn metal anodes for aqueous zinc-ion batteries

Trace Sc-electrolyte additive enabling stable Zn metal anodes for aqueous zinc-ion batteries

Trace Sc 3+ additive (1.0 mol%) is shown to greatly improve the Coulombic efficiency and cycling stability of Zn metal anodes in aqueous ZnSO 4 electrolyte due to the decreased nucleation overpotential and increased kinetics for Zn plating/stripping. Both Zn|Zn and Zn|V 2 O 5 cells show enhanced cyc...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-11, Vol.59 (89), p.13363-13366
Hauptverfasser: Chen, Chun, Li, Liansheng, Long, Zuxin, Liang, Qinghua
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Li, Liansheng
Long, Zuxin
Liang, Qinghua
description Trace Sc 3+ additive (1.0 mol%) is shown to greatly improve the Coulombic efficiency and cycling stability of Zn metal anodes in aqueous ZnSO 4 electrolyte due to the decreased nucleation overpotential and increased kinetics for Zn plating/stripping. Both Zn|Zn and Zn|V 2 O 5 cells show enhanced cycling stability and rate capability in the Sc 3+ -modified electrolyte. Trace Sc 3+ -electrolyte additive in the aqueous ZnSO 4 electrolyte enables stable Zn metal anodes for zinc-ion batteries due to the homogeneous Zn plating/stripping and improved redox kinetics.
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title Trace Sc-electrolyte additive enabling stable Zn metal anodes for aqueous zinc-ion batteries
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