Versatile nicotinamide enabling dendrite-free and efficient deposition for aqueous Zn-I batteries

This study introduces a versatile electrolyte additive, nicotinamide, for zinc anodes, aiming to facilitate uniform deposition and suppress water-induced side reactions. The molecular structure, consisting of a pyridine ring and an amide function group, endows NTA molecules with the ability to regul...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-10, Vol.59 (79), p.11847-1185
Hauptverfasser: Wang, Hejing, Su, Yitian, Yan, Lijing, Zeng, Xiaomin, Chen, Xiaoran, Xiang, Baorui, Ren, Huixin, Ma, Tingli, Ling, Min
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Zusammenfassung:This study introduces a versatile electrolyte additive, nicotinamide, for zinc anodes, aiming to facilitate uniform deposition and suppress water-induced side reactions. The molecular structure, consisting of a pyridine ring and an amide function group, endows NTA molecules with the ability to regulate electrolyte pH, enhance nucleation overpotential, and constrain 2D diffusion of Zn 2+ . As a result, the full battery configuration with this additive achieved an impressive lifespan of over 10 000 cycles. A versatile nicotinamide electrolyte additive for zinc anode is proposed to guide even deposition and suppress water-induced side reactions.
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc03420h