A tri-functional self-supported electrocatalyst featuring mostly NiTeO perovskite for H production methanol-water co-electrolysis

A self-supported NiTeO 3 perovskite is made by deploying an extended hydrothermal tellurization strategy with a restricted Te content, which was found to be exceptionally active towards the oxidation of water and methanol and the reduction of water in 1.0 M KOH where it delivered −10 mA cm −2 at jus...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-10, Vol.59 (85), p.12755-12758
Hauptverfasser: Anantharaj, Sengeni, Li, Mochen, Arulraj, Roshini, Eswaran, Karthik, , Murugesan, Rajini, Maruthapillai, Arthanareeswari, Noda, Suguru
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Zusammenfassung:A self-supported NiTeO 3 perovskite is made by deploying an extended hydrothermal tellurization strategy with a restricted Te content, which was found to be exceptionally active towards the oxidation of water and methanol and the reduction of water in 1.0 M KOH where it delivered −10 mA cm −2 at just −1.54 V for a full cell featuring MOR|HER. An extended hydrothermal treatment of Ni with restricted Te content resulted in a highly active tri-functional electrocatalyst performing the HER, OER, and MOR in alkaline medium.
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc02568c