Triple -defluoroetherification of (trifluoromethyl)alkenes with fluoroalkylated alcohols: access to fluoroalkylated orthoesters C(sp)-F bond cleavage
The triple ipso -defluoroetherification of (trifluoromethyl)alkenes with fluoroalkylated alcohols by C(sp 3 )-F bond cleavage is reported, delivering various fluoroalkylated orthoesters in high yields. This reaction is transition-metal free and gram-scalable, features mild reaction conditions, and t...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2023-06, Vol.59 (53), p.8238-8241 |
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| container_end_page | 8241 |
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| container_issue | 53 |
| container_start_page | 8238 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 59 |
| creator | Nie, Jia Jiang, Huanfeng Zhu, Chuanle |
| description | The triple
ipso
-defluoroetherification of (trifluoromethyl)alkenes with fluoroalkylated alcohols by C(sp
3
)-F bond cleavage is reported, delivering various fluoroalkylated orthoesters in high yields. This reaction is transition-metal free and gram-scalable, features mild reaction conditions, and tolerates diverse functional groups.
Triple
ipso
-defluoroetherification of (trifluoromethyl)alkenes with fluoroalkylated alcohols to synthesize fluoroalkylated orthoesters by C(sp
3
)-F bond cleavage. |
| doi_str_mv | 10.1039/d3cc01760e |
| format | Article |
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-defluoroetherification of (trifluoromethyl)alkenes with fluoroalkylated alcohols by C(sp
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)-F bond cleavage is reported, delivering various fluoroalkylated orthoesters in high yields. This reaction is transition-metal free and gram-scalable, features mild reaction conditions, and tolerates diverse functional groups.
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-defluoroetherification of (trifluoromethyl)alkenes with fluoroalkylated alcohols by C(sp
3
)-F bond cleavage is reported, delivering various fluoroalkylated orthoesters in high yields. This reaction is transition-metal free and gram-scalable, features mild reaction conditions, and tolerates diverse functional groups.
Triple
ipso
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ipso
-defluoroetherification of (trifluoromethyl)alkenes with fluoroalkylated alcohols by C(sp
3
)-F bond cleavage is reported, delivering various fluoroalkylated orthoesters in high yields. This reaction is transition-metal free and gram-scalable, features mild reaction conditions, and tolerates diverse functional groups.
Triple
ipso
-defluoroetherification of (trifluoromethyl)alkenes with fluoroalkylated alcohols to synthesize fluoroalkylated orthoesters by C(sp
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2023-06, Vol.59 (53), p.8238-8241 |
| issn | 1359-7345 1364-548X |
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| recordid | cdi_rsc_primary_d3cc01760e |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Triple -defluoroetherification of (trifluoromethyl)alkenes with fluoroalkylated alcohols: access to fluoroalkylated orthoesters C(sp)-F bond cleavage |
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