A magnetic porous organic polymer: catalytic application in the synthesis of hybrid pyridines with indole, triazole and sulfonamide moieties

Herein, the synthesis and characterization of a triazine-based magnetic ionic porous organic polymer are reported. The structure, morphology, and components of the prepared structure have been investigated with several spectroscopic and microscopic techniques such as FT-IR, EDX, elemental mapping, T...

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Veröffentlicht in:RSC advances 2022-03, Vol.12 (14), p.884-8814
Hauptverfasser: Torabi, Morteza, Yarie, Meysam, Zolfigol, Mohammad Ali, Azizian, Saeid, Gu, Yanlong
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Sprache:eng
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Zusammenfassung:Herein, the synthesis and characterization of a triazine-based magnetic ionic porous organic polymer are reported. The structure, morphology, and components of the prepared structure have been investigated with several spectroscopic and microscopic techniques such as FT-IR, EDX, elemental mapping, TGA/DTA, SEM, TEM, VSM, and BET analysis. Also, catalytic application of the prepared triazine-based magnetic ionic porous organic polymer was investigated for the synthesis of hybrid pyridine derivatives bearing indole, triazole and sulfonamide groups. Furthermore, the prepared hybrid pyridine systems were characterized by FT-IR, 1 H NMR, 13 C NMR and mass analysis. A cooperative vinylogous anomeric-based oxidation pathway was suggested for the synthesis of target molecules. General experimental procedure for the synthesis of hybrid pyridines using TMIPOP as catalyst.
ISSN:2046-2069
2046-2069
DOI:10.1039/d2ra00451h