Thioamide directed iridium()-catalyzed CH arylation of ferrocenes with aryl boronic acids
The first Ir( i )-catalyzed thioamide-assisted C-H arylation of ferrocenes with aryl boronic acids under base-free mild reaction conditions in the presence of Ag 2 CO 3 as an oxidant with eco-friendly 2-MeTHF as a solvent was developed. This reaction has a wide range of substrates (37 examples) and...
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| Veröffentlicht in: | Organic & biomolecular chemistry 2022-07, Vol.2 (29), p.5759-5763 |
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| container_issue | 29 |
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| container_title | Organic & biomolecular chemistry |
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| creator | Ban, Yan Wang, Yingxin Li, Hao Wang, Yan Li, Dianjun Yang, Jinhui |
| description | The first Ir(
i
)-catalyzed thioamide-assisted C-H arylation of ferrocenes with aryl boronic acids under base-free mild reaction conditions in the presence of Ag
2
CO
3
as an oxidant with eco-friendly 2-MeTHF as a solvent was developed. This reaction has a wide range of substrates (37 examples) and functional group tolerance (1894% yields), and provides promising access to aryl thioamide-ferrocene compounds with good yields and regioselectivity.
The Ir(
i
)-catalyzed thioamide-assisted CH arylation of ferrocenes with aryl boronic acids under base-free mild reaction conditions was developed, which has a wide range of substrates and functional group tolerance with good yields and regioselectivity. |
| doi_str_mv | 10.1039/d2ob00863g |
| format | Article |
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i
)-catalyzed thioamide-assisted C-H arylation of ferrocenes with aryl boronic acids under base-free mild reaction conditions in the presence of Ag
2
CO
3
as an oxidant with eco-friendly 2-MeTHF as a solvent was developed. This reaction has a wide range of substrates (37 examples) and functional group tolerance (1894% yields), and provides promising access to aryl thioamide-ferrocene compounds with good yields and regioselectivity.
The Ir(
i
)-catalyzed thioamide-assisted CH arylation of ferrocenes with aryl boronic acids under base-free mild reaction conditions was developed, which has a wide range of substrates and functional group tolerance with good yields and regioselectivity.</description><identifier>ISSN: 1477-0520</identifier><identifier>EISSN: 1477-0539</identifier><identifier>DOI: 10.1039/d2ob00863g</identifier><ispartof>Organic & biomolecular chemistry, 2022-07, Vol.2 (29), p.5759-5763</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Ban, Yan</creatorcontrib><creatorcontrib>Wang, Yingxin</creatorcontrib><creatorcontrib>Li, Hao</creatorcontrib><creatorcontrib>Wang, Yan</creatorcontrib><creatorcontrib>Li, Dianjun</creatorcontrib><creatorcontrib>Yang, Jinhui</creatorcontrib><title>Thioamide directed iridium()-catalyzed CH arylation of ferrocenes with aryl boronic acids</title><title>Organic & biomolecular chemistry</title><description>The first Ir(
i
)-catalyzed thioamide-assisted C-H arylation of ferrocenes with aryl boronic acids under base-free mild reaction conditions in the presence of Ag
2
CO
3
as an oxidant with eco-friendly 2-MeTHF as a solvent was developed. This reaction has a wide range of substrates (37 examples) and functional group tolerance (1894% yields), and provides promising access to aryl thioamide-ferrocene compounds with good yields and regioselectivity.
The Ir(
i
)-catalyzed thioamide-assisted CH arylation of ferrocenes with aryl boronic acids under base-free mild reaction conditions was developed, which has a wide range of substrates and functional group tolerance with good yields and regioselectivity.</description><issn>1477-0520</issn><issn>1477-0539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjr0KwjAYRYMoWH8WdyGjDtWkqa2di9IH6OJU0iS1n7SNJBGpT6-I6Oh0D_dw4SK0oGRDCUu2MtAlIfuInQfIo2Ec-2THkuGXAzJGE2svhNAkjkIPnfIaNG9BKizBKOGUxGBAwq1drX3BHW_6x6tLM8xN33AHusO6wpUyRgvVKYvv4Oq3xKU2ugOBuQBpZ2hU8caq-SenaHk85GnmGyuKq4H2NSl-f9k__wSIVUQo</recordid><startdate>20220727</startdate><enddate>20220727</enddate><creator>Ban, Yan</creator><creator>Wang, Yingxin</creator><creator>Li, Hao</creator><creator>Wang, Yan</creator><creator>Li, Dianjun</creator><creator>Yang, Jinhui</creator><scope/></search><sort><creationdate>20220727</creationdate><title>Thioamide directed iridium()-catalyzed CH arylation of ferrocenes with aryl boronic acids</title><author>Ban, Yan ; Wang, Yingxin ; Li, Hao ; Wang, Yan ; Li, Dianjun ; Yang, Jinhui</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d2ob00863g3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2022</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ban, Yan</creatorcontrib><creatorcontrib>Wang, Yingxin</creatorcontrib><creatorcontrib>Li, Hao</creatorcontrib><creatorcontrib>Wang, Yan</creatorcontrib><creatorcontrib>Li, Dianjun</creatorcontrib><creatorcontrib>Yang, Jinhui</creatorcontrib><jtitle>Organic & biomolecular chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ban, Yan</au><au>Wang, Yingxin</au><au>Li, Hao</au><au>Wang, Yan</au><au>Li, Dianjun</au><au>Yang, Jinhui</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thioamide directed iridium()-catalyzed CH arylation of ferrocenes with aryl boronic acids</atitle><jtitle>Organic & biomolecular chemistry</jtitle><date>2022-07-27</date><risdate>2022</risdate><volume>2</volume><issue>29</issue><spage>5759</spage><epage>5763</epage><pages>5759-5763</pages><issn>1477-0520</issn><eissn>1477-0539</eissn><abstract>The first Ir(
i
)-catalyzed thioamide-assisted C-H arylation of ferrocenes with aryl boronic acids under base-free mild reaction conditions in the presence of Ag
2
CO
3
as an oxidant with eco-friendly 2-MeTHF as a solvent was developed. This reaction has a wide range of substrates (37 examples) and functional group tolerance (1894% yields), and provides promising access to aryl thioamide-ferrocene compounds with good yields and regioselectivity.
The Ir(
i
)-catalyzed thioamide-assisted CH arylation of ferrocenes with aryl boronic acids under base-free mild reaction conditions was developed, which has a wide range of substrates and functional group tolerance with good yields and regioselectivity.</abstract><doi>10.1039/d2ob00863g</doi><tpages>5</tpages></addata></record> |
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| ispartof | Organic & biomolecular chemistry, 2022-07, Vol.2 (29), p.5759-5763 |
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| language | |
| recordid | cdi_rsc_primary_d2ob00863g |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Thioamide directed iridium()-catalyzed CH arylation of ferrocenes with aryl boronic acids |
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