FeO supported Pt single atom catalysts for the selective hydrogenation of cinnamaldehyde
Atomically dispersed Pt species supported on Fe 2 O 3 (Pt 1 /Fe 2 O 3 ) are successfully constructed by a simple ball milling process. In the selective hydrogenation of cinnamaldehyde (CAL), Pt 1 /Fe 2 O 3 achieves an excellent cinnamyl alcohol (COL) selectivity of 81.7% at a CAL conversion of 91.2%...
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Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2022-10, Vol.51 (4), p.15227-15232 |
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Zusammenfassung: | Atomically dispersed Pt species supported on Fe
2
O
3
(Pt
1
/Fe
2
O
3
) are successfully constructed by a simple ball milling process. In the selective hydrogenation of cinnamaldehyde (CAL), Pt
1
/Fe
2
O
3
achieves an excellent cinnamyl alcohol (COL) selectivity of 81.7% at a CAL conversion of 91.2% in pure water medium due to the superior dissociation ability of H
2
and preferential adsorption of CAL
via
C&z.dbd;O.
A simple ball milling method was adopted to prepare single atom catalysts with excellent catalytic properties. |
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ISSN: | 1477-9226 1477-9234 |
DOI: | 10.1039/d2dt02075k |