Flexible translucent persistent luminescent films based on SrMgSiO:Eu,Dy cellulose ether composites

Persistent luminescent materials are present in several recent studies on new applications and novel properties. In this work, we demonstrate, for the first time, the production of translucent flexible persistent composites based on Sr 2 MgSi 2 O 7 :Eu 2+ ,Dy 3+ (SMSO) into cellulose ether matrix fi...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2022-06, Vol.51 (23), p.9138-9143
Hauptverfasser: Fritzen, Douglas L, de Mattos, Elaine A, Petri, Denise F. S, Teixeira, Verônica C, Bonturim, Everton, Rodrigues, Lucas C. V
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Zusammenfassung:Persistent luminescent materials are present in several recent studies on new applications and novel properties. In this work, we demonstrate, for the first time, the production of translucent flexible persistent composites based on Sr 2 MgSi 2 O 7 :Eu 2+ ,Dy 3+ (SMSO) into cellulose ether matrix film. The composite was successfully prepared through a new optimized route of co-precipitation and microwave-assisted annealing followed by (3-aminopropyl)triethoxysilane (APTES) coating and dispersion in hydroxypropyl methylcellulose (HPMC). The SMSO@APTES/HPMC films show persistent luminescence emission at 475 nm (blue) and high transmittance in the visible range. To understand the fine distribution of the nanoparticles in the matrix, we have investigated their structure and dispersion by using Synchrotron Radiation X-ray fluorescence mapping and Scanning Transmission X-ray Microscopy. This innovative composite could bring new perspectives for the class of persistent luminescence materials, enhancing technologies in progress throwing light on new applications never perceived. Production of translucent and flexible films featuring blue persistent luminescence. The films show great transmittance at visible range and can persist for up to 90 min after charging with UV light.
ISSN:1477-9226
1477-9234
DOI:10.1039/d2dt00770c