Anchoring CoS nanowires on NiCoO nanosheet arrays as high-performance electrocatalyst for hydrogen and oxygen evolution

The development of catalysts which can substitute expensive metals to efficiently split water is currently a hot research topic. Here, a multi-layered NF/NiCo 2 O 4 /Co 3 S 4 nanocomposite was prepared on 3D porous nickel foam by hydrothermal and annealing processes. The electrode is a multi-layered, highly conductive and high specific surface area network without a binder, which facilitates electron transport and exposure of active sites, enhances full contact of the electrolyte/electrode interface, and accelerates H 2 and O 2 diffusion during water electrolysis. As expected, NF/NiCo 2 O 4 /Co 3 S 4 exhibits surprising electrocatalytic activity, and only required 71 and 170 mV to reach 10 mA cm −2 in the hydrogen and oxygen evolution reactions, respectively, and exhibited stability up to 36 h. This strategy provides an efficient, durable, and low-cost bifunctional catalyst. The NF/NiCo 2 O 4 /Co 3 S 4 exhibits surprising electrocatalytic activity.