Visible-light-induced C-H functionalization of glycine derivatives by cerium catalysis

A Ce( iii )-catalyzed, visible-light-induced aerobic oxidative dehydrogenative coupling/aromatization reaction between glycine derivatives and alkenes has been developed, which provides an efficient approach for the synthesis of quinoline derivatives and post-modification of oligopeptides containing glycine residues under mild conditions without the need for external photosensitizers. A Ce( iii )-catalyzed, visible-light-induced aerobic oxidative cross-dehydrogenative coupling/aromatization between glycine derivatives and alkenes is achieved without any external photosensitizer or additive.