Gas-phase organometallic catalysis in MFM-300(Sc) provided by switchable dynamic metal sites

MFM-300(Sc) was explored as a catalyst for the gas-phase hydrogenation of acetone. The catalysis results support the presence of non-permanent open Sc( iii ) sites within the structure due to the requirement of Lewis acid sites for the reaction to proceed. The open Sc( iii ) sites are generated in situ due to the presence of hemilabile Sc-O bonds. MFM-300(Sc) showed high mechanical and chemical stability, and the crystalline structure was maintained after the catalytic reaction. The catalytic activity of the material was quantified by performing a gas-phase reaction using a continuous flow reactor. The acetone conversion in MFM-300(Sc) was estimated to be 27.7% with no loss of activity after catalytic cycles. MFM-300(Sc) was explored as a catalyst for the gas-phase hydrogenation of acetone. The reaction was driven by Sc( iii ) dynamics sites.