Recent advances in catalytic pnictogen bond forming reactions dehydrocoupling and hydrofunctionalization

An examination of several catalytic reactions among the group 15 elements is presented. The connections between the chemistry of the pnictogens can sometimes be challenging, but aspects of metal-pnictogen reactivity are the key. The connecting reactivity comes from metal-catalyzed transformations su...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-01, Vol.59 (1), p.1258-1273
Hauptverfasser: Reuter, Matthew B, Seth, Dennis M, Javier-Jiménez, Diego R, Finfer, Emma J, Beretta, Evan A, Waterman, Rory
Format: Artikel
Sprache:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 1273
container_issue 1
container_start_page 1258
container_title Chemical communications (Cambridge, England)
container_volume 59
creator Reuter, Matthew B
Seth, Dennis M
Javier-Jiménez, Diego R
Finfer, Emma J
Beretta, Evan A
Waterman, Rory
description An examination of several catalytic reactions among the group 15 elements is presented. The connections between the chemistry of the pnictogens can sometimes be challenging, but aspects of metal-pnictogen reactivity are the key. The connecting reactivity comes from metal-catalyzed transformations such as dehydrocoupling and hydrofunctionalization. Pivotal mechanistic insights from E-N heterodehydrocoupling have informed the development of highly active catalysts for these reactions. Metal-amido nucleophilicity is often at the core of this reactivity, which diverges from phosphine and arsine dehydrocoupling. Nucleophilicity connects to the earliest understanding of hydrophosphination catalysis, but more recent catalysts are leveraging enhanced insertion activity through photolysis. This photocatalysis extends to hydroarsination, which may also have more metal-arsenido nucleophilicity than anticipated. However, metal-catalyzed arsinidene chemistry foreshadowed related phosphinidene chemistry by years. This examination shows the potential for greater influence of individual discoveries and understanding to leverage new advances between these elements, and it also suggests that the chemistry of heavier elements may have more influence on what is possible with lighter elements. The metal-pnictogen bond has rich and varied reactivity. The differences and similarities down the group and impacts on catalytic reactions with these elements is explored in this Feature.
doi_str_mv 10.1039/d2cc06143k
format Article
fullrecord <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_d2cc06143k</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>d2cc06143k</sourcerecordid><originalsourceid>FETCH-rsc_primary_d2cc06143k3</originalsourceid><addsrcrecordid>eNqFjj0LwjAYhIMo-Lm4C_kD1ca0fsyiOIuDW3l9k2q0vilJFOqv14rg6C133D3DMTYU8VjEcjlRU8R4JhJ5bbCOkLMkSpPFoVnndBnNZZK2Wdf7S_yWSBcddt5p1BQ4qAcQas8NcYQARRUM8pIMBnvSxI-WFM-tuxk6cacBg7HkudLnSjmL9l4W9QJv6tPkd_ogUJgn1KHPWjkUXg--3mOjzXq_2kbOY1Y6cwNXZb_78t_-AvWoS6Y</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Recent advances in catalytic pnictogen bond forming reactions dehydrocoupling and hydrofunctionalization</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Reuter, Matthew B ; Seth, Dennis M ; Javier-Jiménez, Diego R ; Finfer, Emma J ; Beretta, Evan A ; Waterman, Rory</creator><creatorcontrib>Reuter, Matthew B ; Seth, Dennis M ; Javier-Jiménez, Diego R ; Finfer, Emma J ; Beretta, Evan A ; Waterman, Rory</creatorcontrib><description>An examination of several catalytic reactions among the group 15 elements is presented. The connections between the chemistry of the pnictogens can sometimes be challenging, but aspects of metal-pnictogen reactivity are the key. The connecting reactivity comes from metal-catalyzed transformations such as dehydrocoupling and hydrofunctionalization. Pivotal mechanistic insights from E-N heterodehydrocoupling have informed the development of highly active catalysts for these reactions. Metal-amido nucleophilicity is often at the core of this reactivity, which diverges from phosphine and arsine dehydrocoupling. Nucleophilicity connects to the earliest understanding of hydrophosphination catalysis, but more recent catalysts are leveraging enhanced insertion activity through photolysis. This photocatalysis extends to hydroarsination, which may also have more metal-arsenido nucleophilicity than anticipated. However, metal-catalyzed arsinidene chemistry foreshadowed related phosphinidene chemistry by years. This examination shows the potential for greater influence of individual discoveries and understanding to leverage new advances between these elements, and it also suggests that the chemistry of heavier elements may have more influence on what is possible with lighter elements. The metal-pnictogen bond has rich and varied reactivity. The differences and similarities down the group and impacts on catalytic reactions with these elements is explored in this Feature.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d2cc06143k</identifier><ispartof>Chemical communications (Cambridge, England), 2023-01, Vol.59 (1), p.1258-1273</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Reuter, Matthew B</creatorcontrib><creatorcontrib>Seth, Dennis M</creatorcontrib><creatorcontrib>Javier-Jiménez, Diego R</creatorcontrib><creatorcontrib>Finfer, Emma J</creatorcontrib><creatorcontrib>Beretta, Evan A</creatorcontrib><creatorcontrib>Waterman, Rory</creatorcontrib><title>Recent advances in catalytic pnictogen bond forming reactions dehydrocoupling and hydrofunctionalization</title><title>Chemical communications (Cambridge, England)</title><description>An examination of several catalytic reactions among the group 15 elements is presented. The connections between the chemistry of the pnictogens can sometimes be challenging, but aspects of metal-pnictogen reactivity are the key. The connecting reactivity comes from metal-catalyzed transformations such as dehydrocoupling and hydrofunctionalization. Pivotal mechanistic insights from E-N heterodehydrocoupling have informed the development of highly active catalysts for these reactions. Metal-amido nucleophilicity is often at the core of this reactivity, which diverges from phosphine and arsine dehydrocoupling. Nucleophilicity connects to the earliest understanding of hydrophosphination catalysis, but more recent catalysts are leveraging enhanced insertion activity through photolysis. This photocatalysis extends to hydroarsination, which may also have more metal-arsenido nucleophilicity than anticipated. However, metal-catalyzed arsinidene chemistry foreshadowed related phosphinidene chemistry by years. This examination shows the potential for greater influence of individual discoveries and understanding to leverage new advances between these elements, and it also suggests that the chemistry of heavier elements may have more influence on what is possible with lighter elements. The metal-pnictogen bond has rich and varied reactivity. The differences and similarities down the group and impacts on catalytic reactions with these elements is explored in this Feature.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjj0LwjAYhIMo-Lm4C_kD1ca0fsyiOIuDW3l9k2q0vilJFOqv14rg6C133D3DMTYU8VjEcjlRU8R4JhJ5bbCOkLMkSpPFoVnndBnNZZK2Wdf7S_yWSBcddt5p1BQ4qAcQas8NcYQARRUM8pIMBnvSxI-WFM-tuxk6cacBg7HkudLnSjmL9l4W9QJv6tPkd_ogUJgn1KHPWjkUXg--3mOjzXq_2kbOY1Y6cwNXZb_78t_-AvWoS6Y</recordid><startdate>20230131</startdate><enddate>20230131</enddate><creator>Reuter, Matthew B</creator><creator>Seth, Dennis M</creator><creator>Javier-Jiménez, Diego R</creator><creator>Finfer, Emma J</creator><creator>Beretta, Evan A</creator><creator>Waterman, Rory</creator><scope/></search><sort><creationdate>20230131</creationdate><title>Recent advances in catalytic pnictogen bond forming reactions dehydrocoupling and hydrofunctionalization</title><author>Reuter, Matthew B ; Seth, Dennis M ; Javier-Jiménez, Diego R ; Finfer, Emma J ; Beretta, Evan A ; Waterman, Rory</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d2cc06143k3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2023</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Reuter, Matthew B</creatorcontrib><creatorcontrib>Seth, Dennis M</creatorcontrib><creatorcontrib>Javier-Jiménez, Diego R</creatorcontrib><creatorcontrib>Finfer, Emma J</creatorcontrib><creatorcontrib>Beretta, Evan A</creatorcontrib><creatorcontrib>Waterman, Rory</creatorcontrib><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Reuter, Matthew B</au><au>Seth, Dennis M</au><au>Javier-Jiménez, Diego R</au><au>Finfer, Emma J</au><au>Beretta, Evan A</au><au>Waterman, Rory</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Recent advances in catalytic pnictogen bond forming reactions dehydrocoupling and hydrofunctionalization</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2023-01-31</date><risdate>2023</risdate><volume>59</volume><issue>1</issue><spage>1258</spage><epage>1273</epage><pages>1258-1273</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>An examination of several catalytic reactions among the group 15 elements is presented. The connections between the chemistry of the pnictogens can sometimes be challenging, but aspects of metal-pnictogen reactivity are the key. The connecting reactivity comes from metal-catalyzed transformations such as dehydrocoupling and hydrofunctionalization. Pivotal mechanistic insights from E-N heterodehydrocoupling have informed the development of highly active catalysts for these reactions. Metal-amido nucleophilicity is often at the core of this reactivity, which diverges from phosphine and arsine dehydrocoupling. Nucleophilicity connects to the earliest understanding of hydrophosphination catalysis, but more recent catalysts are leveraging enhanced insertion activity through photolysis. This photocatalysis extends to hydroarsination, which may also have more metal-arsenido nucleophilicity than anticipated. However, metal-catalyzed arsinidene chemistry foreshadowed related phosphinidene chemistry by years. This examination shows the potential for greater influence of individual discoveries and understanding to leverage new advances between these elements, and it also suggests that the chemistry of heavier elements may have more influence on what is possible with lighter elements. The metal-pnictogen bond has rich and varied reactivity. The differences and similarities down the group and impacts on catalytic reactions with these elements is explored in this Feature.</abstract><doi>10.1039/d2cc06143k</doi><tpages>16</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1359-7345
ispartof Chemical communications (Cambridge, England), 2023-01, Vol.59 (1), p.1258-1273
issn 1359-7345
1364-548X
language
recordid cdi_rsc_primary_d2cc06143k
source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
title Recent advances in catalytic pnictogen bond forming reactions dehydrocoupling and hydrofunctionalization
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-04T10%3A33%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Recent%20advances%20in%20catalytic%20pnictogen%20bond%20forming%20reactions%20dehydrocoupling%20and%20hydrofunctionalization&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Reuter,%20Matthew%20B&rft.date=2023-01-31&rft.volume=59&rft.issue=1&rft.spage=1258&rft.epage=1273&rft.pages=1258-1273&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/d2cc06143k&rft_dat=%3Crsc%3Ed2cc06143k%3C/rsc%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true