Dynamic [1]rotaxanes a reversible covalent bond and host-guest anion recognition
Bambus[6]uril-based [1]rotaxanes were formed quantitatively, utilizing a bis(acyloxy)iodate( i ) reversible covalent bond and host-guest anion recognition. These novel [1]rotaxanes exhibited a dynamic nature facilitating carboxylate component exchange reactions in acetonitrile. Bambus[6]uril-based [...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2022-03, Vol.58 (23), p.3815-3818 |
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Zusammenfassung: | Bambus[6]uril-based [1]rotaxanes were formed quantitatively, utilizing a bis(acyloxy)iodate(
i
) reversible covalent bond and host-guest anion recognition. These novel [1]rotaxanes exhibited a dynamic nature facilitating carboxylate component exchange reactions in acetonitrile.
Bambus[6]uril-based [1]rotaxanes were formed quantitatively, utilizing the bis(acyloxy)iodate(
i
) reversible covalent bond and host-guest anion recognition. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/d2cc00779g |