Dynamic [1]rotaxanes a reversible covalent bond and host-guest anion recognition

Bambus[6]uril-based [1]rotaxanes were formed quantitatively, utilizing a bis(acyloxy)iodate( i ) reversible covalent bond and host-guest anion recognition. These novel [1]rotaxanes exhibited a dynamic nature facilitating carboxylate component exchange reactions in acetonitrile. Bambus[6]uril-based [...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-03, Vol.58 (23), p.3815-3818
Hauptverfasser: Del Mauro, Arico, Kokan, Zoran, Šindelá, Vladimír
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Zusammenfassung:Bambus[6]uril-based [1]rotaxanes were formed quantitatively, utilizing a bis(acyloxy)iodate( i ) reversible covalent bond and host-guest anion recognition. These novel [1]rotaxanes exhibited a dynamic nature facilitating carboxylate component exchange reactions in acetonitrile. Bambus[6]uril-based [1]rotaxanes were formed quantitatively, utilizing the bis(acyloxy)iodate( i ) reversible covalent bond and host-guest anion recognition.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc00779g