Studies on structural, dielectric and optical properties of (BaCa)(TiSn)NaNbO lead-free ceramics

(Ba 0.95 Ca 0.05 ) 1− x (Ti 0.8 Sn 0.2 ) 1− x Na x Nb x O 3 (BCNTSNO 3 ) lead-free ceramics with compositions ( x = 0.75, 0.8 and 0.85) were synthesized through the traditional solid-state reaction method. X-ray powder diffraction analysis showed the formation of a single phase compound crystallized in tetragonal space group P 4 mm . The evolution of Raman spectra displayed a disorder introduced into the structure, which favors a ferroelectric relaxor behavior. The dependence of the dielectric properties on temperature exhibited two composition ranges with different behaviors. Ferroelectric relaxor properties were observed for the compositions x < 0.85 and the classical ferroelectric behavior for x = 0.85. Lead free (Ba 0.95 Ca 0.05 ) 1− x (Ti 0.8 Sn 0.2 ) 1− x Na x Nb x O 3 ceramics exhibited larger dielectric constants than those of parent crystal NaNbO 3 , suggesting that it is a good candidate for lead-free ceramics in several industrial applications. Using UV-Vis spectroscopy, the optical band gap energy of ceramics (Ba 0.95 Ca 0.05 ) 1− x (Ti 0.8 Sn 0.2 ) 1− x Na x Nb x O 3 is found at 2.89, 2.92, and 3.05 eV for x = 0.75, 0.8 and 0.85, respectively. (Ba 0.95 Ca 0.05 ) 1− x (Ti 0.8 Sn 0.2 ) 1− x Na x Nb x O 3 (BCNTSNO 3 ) lead-free ceramics with compositions ( x = 0.75, 0.8 and 0.85) were synthesized through the traditional solid-state reaction method.