Fabrication of nanoscale core-shell structured lead azide/porous carbon based on a metal-organic framework with high safety performance

In this work, we used a lead-containing MOF material as the precursor material to prepare a carbon-based lead azide with nano-scale lead azide coated with a carbon shell (LA/C) through carbonization and azide processes. The lead-containing MOF precursor materials, carbide intermediates, and lead azi...

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Veröffentlicht in:New journal of chemistry 2022-03, Vol.46 (1), p.4864-487
Hauptverfasser: Yan, Zhenzhan, Yang, Li, Tong, Wenchao, Han, Ji-Min
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Sprache:eng
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Zusammenfassung:In this work, we used a lead-containing MOF material as the precursor material to prepare a carbon-based lead azide with nano-scale lead azide coated with a carbon shell (LA/C) through carbonization and azide processes. The lead-containing MOF precursor materials, carbide intermediates, and lead azide/carbon with core-shell structures have all been characterized in detail. The exhaustive characterizations demonstrate that the electrostatic sensitivity of LA/C is reduced to 1.84 J, and the flame sensitivity is increased to 22 cm, thanks to the coating effect and excellent electrical and thermal conductivity of the carbon shell. High-speed photography of the initiation process shows that the initiation process of LA/C is extremely short (less than 1 ms) and LA/C has excellent detonation ability. The properties of LA/C are better than those of previously reported pure LA and most modified LA materials. These findings provide a new perspective for the synthesis of superior performance carbon-based primary explosives with a core-shell structure. Carbon-based lead azide with nano-scale lead azide coated with a carbon shell (LA/C) was prepared using a lead-containing MOF material. The prepared LA/C exhibits excellent electrostatic sensitivity (1.84 J), higher LA content (85%), and better ignition ability (22 cm) compared to other reported modified LA materials.
ISSN:1144-0546
1369-9261
DOI:10.1039/d1nj06060k