Understanding the role of redox properties and NO adsorption over MnFeO for NH-SCR

Widening the operational temperature window of the selective catalytic reduction of NO by NH 3 (NH 3 -SCR) is a challenge to meet the increasingly stringent emission control regulations for NO x . Hence, MnFeO x with different molar ratios were prepared and investigated for NH 3 -SCR. Mn-Fe-0.2 (Mn/Fe molar ratio of 0.2) eliminates more than 80% of NO x in the temperature range of 50 to 360 °C with a N 2 selectivity of higher than 90%. In addition, it also presents excellent SO 2 /H 2 O tolerance. Doping Mn not only inhibits the phase transformation of iron oxide (Fe 2 O 3 ) but also strengthens the interaction between MnO x and Fe 2 O 3 due to the electron transfer between them, which leads to the formation of Mn-O-Fe. Meanwhile, the amounts of acid, redox properties, and NO adsorption could also be tuned. The generation of different types of nitrite/nitrate is dependent on the redox properties and NO adsorption strength, whereas the activity of nitrite/nitrate functions in a different reaction temperature zone. Therefore, tuning for moderate redox activity and the NO adsorption strength will help to extend the operational temperature window. Widening the operational temperature window of the selective catalytic reduction of NO by NH 3 (NH 3 -SCR) is a challenge to meet the increasingly stringent emission control regulations for NO x .