The role of surface stoichiometry in NO gas sensing using single and multiple nanobelts of tin oxide

Typically used semiconducting metal oxides (SMOs) consist of several varying factors that affect gas sensor response, including film thickness, grain size, and notably the grain-grain junctions within the active device volume, which complicates the analysis and optimisation of sensor response. In comparison, devices containing a single nanostructured element do not present grain-grain junctions, and therefore present an excellent platform to comprehend the correlation between nanostructure surface stoichiometry and sensor response to the depletion layer (Debye length, L D ) variation after the analyte gas adsorption/chemisorption. In this work, nanofabricated devices containing SnO 2 and Sn 3 O 4 individual nanobelts of different thicknesses were used to estimate their L D after NO 2 exposure. In the presence of 40 ppm of NO 2 at 150 °C, L D of 12 nm and 8 nm were obtained for SnO 2 and Sn 3 O 4 , respectively. These values were associated to the sensor signals measured using multiple nanobelts onto interdigitated electrodes, outlining that the higher sensor signal of the Sn 4+ surface (up to 708 for 100 ppm NO 2 at 150°) in comparison with the Sn 2+ (up to 185) can be explained based on a less depleted initial state and a lower surface electron affinity caused by the Lewis acid/base interactions with oxygen species from the baseline gas. To support the proposed mechanisms, we investigated the gas sensor response of SnO 2 nanobelts with a higher quantity of oxygen vacancies and correlated the results to the SnO system. Single-nanobelt gas sensor devices were nanofabricated to estimate Sn 3 O 4 and SnO 2 Debye length ( L D ) in presence of NO 2 , and gas-solid interactions between O species/NO 2 and Sn 2+ /Sn 4+ surfaces were proposed based on tin oxide sensor signals.