generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes

generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes

Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall carbohalogenation process leads to good isolated yields. Atom transfer radical addition of alkyl halides to alke...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-02, Vol.58 (13), p.2124-2127
Hauptverfasser: Liautard, Virginie, Delgado, Marine, Colin, Boris, Chabaud, Laurent, Michaud, Guillaume, Pucheault, Mathieu
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Zusammenfassung:Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall carbohalogenation process leads to good isolated yields. Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes.
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc06390a