Frustrated Lewis pairs with thermally activated delayed fluorescence properties: activation of formaldehyde

Activation of formaldehyde (FA) by frustrated Lewis pairs (FLPs) that are comprised of bulky phosphines having a carbazolyl donor-triarylboryl acceptor unit and B(C 6 F 5 ) 3 led to the formation of FLP-FA adducts that exhibit a thermally activated delayed fluorescence. Activation of formaldehyde (F...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2020-10, Vol.49 (38), p.13198-1321
Hauptverfasser:	Lee, Young Hoon, Nam, Eun Bi, Lee, Junseong, Lee, Sang Uck, Lee, Min Hyung
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Adducts Crystallography Fluorescence Formaldehyde NMR Nuclear magnetic resonance Phosphines
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Zusammenfassung:	Activation of formaldehyde (FA) by frustrated Lewis pairs (FLPs) that are comprised of bulky phosphines having a carbazolyl donor-triarylboryl acceptor unit and B(C 6 F 5 ) 3 led to the formation of FLP-FA adducts that exhibit a thermally activated delayed fluorescence. Activation of formaldehyde (FA) by frustrated Lewis pairs (FLPs) consisting of bulky phosphines with a donor-acceptor unit and B(C 6 F 5 ) 3 led to the formation of FLP-FA adducts that exhibit a thermally activated delayed fluorescence.
ISSN:	1477-9226 1477-9234
DOI:	10.1039/d0dt02507k