Field-induced slow magnetic relaxation in two interpenetrated cobalt() metal-organic framework isomers

Field-induced slow magnetic relaxation was observed in two interpenetrated cobalt( ii ) metal-organic framework (MOF) isomers constructed from a dual-functional ligand 1 H -benzimidazole-5-carboxylic acid, which represent the first example of MOF isomers showing field-induced single-ion magnet behav...

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Veröffentlicht in:CrystEngComm 2020-08, Vol.22 (32), p.5275-5279
Hauptverfasser: Wei, Xiao-Qin, Shao, Dong, Xue, Cai-Long, Qu, Xing-Yu, Chai, Jie, Li, Jian-Qing, Du, Yi-En, Chen, Yong-Qiang
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Sprache:eng
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Zusammenfassung:Field-induced slow magnetic relaxation was observed in two interpenetrated cobalt( ii ) metal-organic framework (MOF) isomers constructed from a dual-functional ligand 1 H -benzimidazole-5-carboxylic acid, which represent the first example of MOF isomers showing field-induced single-ion magnet behavior. Two interpenetrated cobalt( ii ) metal-organic framework (MOF) isomers were successfully synthesized and magnetically characterized. These compounds are the first example of MOF isomers showing field-induced single-ion magnet behavior.
ISSN:1466-8033
1466-8033
DOI:10.1039/d0ce00979b