Engineering of a new single-crystal multi-ionic fast and high-light-yield scintillation material (Gd-Y)AlGaO:Ce,Mg

A single crystal scintillation material (Gd 0.5 -Y 0.5 ) 3 Al 2 Ga 3 O 12 (GYAGG) doped with Ce and codoped with Mg at a small concentration was grown by the Czochralski technique and studied for its scintillation properties for the first time. The Czochralski technique enabled this multi-ionic garn...

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Veröffentlicht in:CrystEngComm 2020-04, Vol.22 (14), p.252-256
Hauptverfasser: Korzhik, Mikhail, Alenkov, Vladimir, Buzanov, Oleg, Dosovitskiy, Georgy, Fedorov, Andrei, Kozlov, Dmitry, Mechinsky, Vitaly, Nargelas, Saulius, Tamulaitis, Gintautas, Vaitkevi ius, Augustas
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Sprache:eng
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Zusammenfassung:A single crystal scintillation material (Gd 0.5 -Y 0.5 ) 3 Al 2 Ga 3 O 12 (GYAGG) doped with Ce and codoped with Mg at a small concentration was grown by the Czochralski technique and studied for its scintillation properties for the first time. The Czochralski technique enabled this multi-ionic garnet to be produced from a melt in a single crystal form and allowed the problems of codoping peculiar to this material in a ceramic form to be solved. Due to codoping, the scintillation kinetics of a single crystal is shorter than that of GYAGG ceramics produced before. The scintillation properties of GYAGG were found to be superior to those of the solely Ce-doped or Mg-codoped Gd 3 Al 2 Ga 3 O 12 crystal. The light yield of GYAGG:Ce,Mg was found to be 52 000 ph MeV −1 , the coefficient of the light yield temperature dependence in the temperature range 20-100 °C was equal to 0.37%/°C, and the scintillation decay time constant was 50 ns. A single crystal scintillation material (Gd 0.5 -Y 0.5 ) 3 Al 2 Ga 3 O 12 (GYAGG) doped with Ce and codoped with Mg at a small concentration was grown by the Czochralski technique and studied for its scintillation properties for the first time.
ISSN:1466-8033
DOI:10.1039/d0ce00105h