Direct imidation of lactones catalytic oxo/imido heterometathesis

Direct imidation of lactones catalytic oxo/imido heterometathesis

We report the first examples of direct imidation of lactones giving the corresponding cyclic imidates via oxo/imido heterometathesis with N -sulfinylamines catalysed by a well-defined silica-supported Ti imido complex. We report the first examples of catalytic oxo/imido heterometathesis reactions th...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2021-03, Vol.57 (21), p.2625-2628
Hauptverfasser: Rumyantsev, Andrey V, Pichugov, Andrey V, Bushkov, Nikolai S, Aleshin, Dmitry Yu, Strelkova, Tatyana V, Lependina, Olga L, Zhizhko, Pavel A, Zarubin, Dmitry N
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Zusammenfassung:We report the first examples of direct imidation of lactones giving the corresponding cyclic imidates via oxo/imido heterometathesis with N -sulfinylamines catalysed by a well-defined silica-supported Ti imido complex. We report the first examples of catalytic oxo/imido heterometathesis reactions that involve carboxylic acid derivatives (lactones).
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc08274k