A hydrogen-bonded organic framework based on redox-active tri(dithiolylidene)cyclohexanetrione

A hydrogen-bonded organic framework based on redox-active tri(dithiolylidene)cyclohexanetrione

Redox-active hexakis(4-carboxyphenyl) tri(dithiolylidene)cyclohexanetrione (CPDC) was synthesized. The CPDC-based porous framework, constructed via anomalistic helical hydrogen-bonding, exhibites permanent porosity and photoconductivity. The porous architecture derived from a tri(dithiolylidene)cycl...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2021-01, Vol.57 (9), p.1157-116
Hauptverfasser: Shivakumar, Kilingaru I, Noro, Shin-ichiro, Yamaguchi, Yuna, Ishigaki, Yusuke, Saeki, Akinori, Takahashi, Kiyonori, Nakamura, Takayoshi, Hisaki, Ichiro
Format: Artikel
Sprache:eng
Schlagworte:
Crystallography
Electrochemistry
Hydrogen bonding
Photoconductivity
Porosity
Thermal analysis
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Zusammenfassung:Redox-active hexakis(4-carboxyphenyl) tri(dithiolylidene)cyclohexanetrione (CPDC) was synthesized. The CPDC-based porous framework, constructed via anomalistic helical hydrogen-bonding, exhibites permanent porosity and photoconductivity. The porous architecture derived from a tri(dithiolylidene)cyclohexanetrione derivative reveals the crucial role of bite angle ( ) in designing the hydrogen-bonded organic frameworks (HOFs).
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc07776c