Synthetic and natural MOR zeolites as high-capacity adsorbents for the removal of nitrous oxide

N 2 O is typically present as a trace gas in chemical processes, but its emission causes serious environmental issues. We herein demonstrate that ion-exchanged mordenite zeolites (framework code: MOR) can exhibit high capacities for N 2 O adsorption under ambient conditions. In particular, a natural...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2021-02, Vol.57 (11), p.1312-1315
Hauptverfasser: Yamashita, Keita, Liu, Zhendong, Iyoki, Kenta, Chen, Ching-Tien, Miyagi, Shoko, Yanaba, Yutaka, Yamauchi, Yusuke, Okubo, Tatsuya, Wakihara, Toru
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Sprache:eng
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Zusammenfassung:N 2 O is typically present as a trace gas in chemical processes, but its emission causes serious environmental issues. We herein demonstrate that ion-exchanged mordenite zeolites (framework code: MOR) can exhibit high capacities for N 2 O adsorption under ambient conditions. In particular, a natural MOR zeolite gives an adsorption capacity as high as 0.34 mmol-N 2 O per g-zeolite (1 atm, 25 °C), representing the best performing material among all zeolite-based adsorbents reported so far. The results contribute toward a comprehensive understanding of the structure-activity relationship and offer insights to establishing a zeolite-based adsorption system for enriching or removing N 2 O. Ion-exchanged MOR zeolite gives an adsorption capacity as high as 0.34 mmol-N 2 O/g-zeolite (1 atm, 25 °C), representing the best performing material among all zeolite-based N 2 O adsorbents reported so far.
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc07511f