Synthetic and natural MOR zeolites as high-capacity adsorbents for the removal of nitrous oxide
N 2 O is typically present as a trace gas in chemical processes, but its emission causes serious environmental issues. We herein demonstrate that ion-exchanged mordenite zeolites (framework code: MOR) can exhibit high capacities for N 2 O adsorption under ambient conditions. In particular, a natural...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2021-02, Vol.57 (11), p.1312-1315 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | N
2
O is typically present as a trace gas in chemical processes, but its emission causes serious environmental issues. We herein demonstrate that ion-exchanged mordenite zeolites (framework code: MOR) can exhibit high capacities for N
2
O adsorption under ambient conditions. In particular, a natural MOR zeolite gives an adsorption capacity as high as 0.34 mmol-N
2
O per g-zeolite (1 atm, 25 °C), representing the best performing material among all zeolite-based adsorbents reported so far. The results contribute toward a comprehensive understanding of the structure-activity relationship and offer insights to establishing a zeolite-based adsorption system for enriching or removing N
2
O.
Ion-exchanged MOR zeolite gives an adsorption capacity as high as 0.34 mmol-N
2
O/g-zeolite (1 atm, 25 °C), representing the best performing material among all zeolite-based N
2
O adsorbents reported so far. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/d0cc07511f |