Hybridization-activated new deep ultraviolet transparent nonlinear optical material Ba[Al(PO)](PO)(PO) with balanced overall performance and parsimony-forbidden structure
A new nonlinear optical material, Ba 11 [Al(PO 4 ) 4 ](P 2 O 7 )(PO 4 ) 3 , was rationally synthesized via the hybridization of three types of anionic groups, namely [AlO 4 ] 5− , [PO 4 ] 3− and [P 2 O 7 ] 4− , via a spontaneous nucleation method. Ba 11 [Al(PO 4 ) 4 ](P 2 O 7 )(PO 4 ) 3 was characte...
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| Veröffentlicht in: | Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2019-12, Vol.7 (48), p.15162-15165 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
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| Zusammenfassung: | A new nonlinear optical material, Ba
11
[Al(PO
4
)
4
](P
2
O
7
)(PO
4
)
3
, was rationally synthesized
via
the hybridization of three types of anionic groups, namely [AlO
4
]
5−
, [PO
4
]
3−
and [P
2
O
7
]
4−
,
via
a spontaneous nucleation method. Ba
11
[Al(PO
4
)
4
](P
2
O
7
)(PO
4
)
3
was characterized with high thermal stability, deep ultraviolet transparency and moderate second-order optical nonlinearity, which were favourable for practical applications.
Hybridization-enabled approach of a new deep-ultraviolet transparent nonlinear-optical material Ba
11
[Al(PO
4
)
4
](P
2
O
7
)(PO
4
)
3
exhibiting balanced overall performance and featuring three types of chromophores. |
|---|---|
| ISSN: | 2050-7526 2050-7534 |
| DOI: | 10.1039/c9tc05648c |