Dealloyed porous gold anchored by generated graphene sheets as high activity catalyst for methanol electro-oxidation reaction

A novel one-step method to prepare the nanocomposites of reduced graphene oxide (RGO)/nanoporous gold (NPG) is realized by chemically dealloying an Al 2 Au precursor. The RGO nanosheets anchored on the surface of NPG have a cicada wing like shape and act as both conductive agent and buffer layer to...

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Veröffentlicht in:RSC advances 2020-01, Vol.1 (3), p.1666-1678
Hauptverfasser: Xu, Hui, Liu, Shuai, Pu, Xiaoliang, Shen, Kechang, Zhang, Laichang, Wang, Xiaoguang, Qin, Jingyu, Wang, Weimin
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Zusammenfassung:A novel one-step method to prepare the nanocomposites of reduced graphene oxide (RGO)/nanoporous gold (NPG) is realized by chemically dealloying an Al 2 Au precursor. The RGO nanosheets anchored on the surface of NPG have a cicada wing like shape and act as both conductive agent and buffer layer to improve the catalytic ability of NPG for methanol electro-oxidation reaction (MOR). This improvement can also be ascribed to the microstructure change of NPG in dealloying with RGO. This work inspires a facile and economic method to prepare the NPG based catalyst for MOR. A novel one-step method to prepare the nanocomposites of reduced graphene oxide (RGO)/nanoporous gold (NPG) is realized by chemically dealloying an Al 2 Au precursor.
ISSN:2046-2069
DOI:10.1039/c9ra09821f