High temperature Fe() spin crossover behaviours in three unprecedented Fe-M-Fe (M = Fe, Cd) linear trinuclear complexes

High temperature Fe() spin crossover behaviours in three unprecedented Fe-M-Fe (M = Fe, Cd) linear trinuclear complexes

An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H 3 ATD) was used to synthesize three unprecedented Fe III -M II -Fe III (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal Fe III ions. An azo-based ligand of azotet...

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Veröffentlicht in:Inorganic chemistry frontiers 2020-04, Vol.7 (7), p.1526-1531
Hauptverfasser: Ouyang, Zhi-Jian, Mo, Xiao-Ying, Yang, Meng, Zhong, Li, Chen, Wen-Bin, Gao, Song, Dong, Wen
Format: Artikel
Sprache:eng
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Zusammenfassung:An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H 3 ATD) was used to synthesize three unprecedented Fe III -M II -Fe III (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal Fe III ions. An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H 3 ATD) was used to synthesize three Fe III -M II -Fe III (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal Fe III ions.
ISSN:2052-1553
DOI:10.1039/c9qi01560d