Surface modification strategy for fluorescence solvatochromism of carbon dots prepared from -phenylenediamine

The fluorescence solvatochromism of p -phenylenediamine-derived carbon dots (CDs) was modulated through surface modification with decanoic acid or perfluorodecanoic acid. This is attributed to the adjustment of the dipole interaction between solvent molecules and the CD surface in terms of steric hindrance of a surface modifier and polarization of the modified CD surface. Surface modification of p -phenylenediamine-derived carbon dots with decanoic acid and perfluorodecanoic acid successfully modulated fluorescence solvatochromism.