Enhanced methane activation on diluted metal-metal ensembles under an electric field: breakthrough in alloy catalysis
Methane activation on diluted metal ensembles is a challenging task in the field of alloy chemistry. This report describes that synergy between an electric field and Pd-Zn alloy allows improved catalytic activities in the steam reforming of methane. Because of surface protonics, Pd-Pd ensembles are...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2019, Vol.55 (47), p.6693-6695 |
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Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Methane activation on diluted metal ensembles is a challenging task in the field of alloy chemistry. This report describes that synergy between an electric field and Pd-Zn alloy allows improved catalytic activities in the steam reforming of methane. Because of surface protonics, Pd-Pd ensembles are no longer needed. Ligand effects facilitate methane conversion.
Synergy between an electric field and Pd-Zn alloy allows improved catalytic activities in the steam reforming of methane. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c9cc02794g |