Multiple functional groups in UiO-66 improve chemical warfare agent simulant degradation

A library of 26 mixed ligand UiO-66 analogs was synthesized, characterized, and screened for catalytic degradation of the chemical warfare agent (CWA) simulant dimethyl 4-nitrophenylphosphate (DMNP). The MOFs were screened and compared to physical mixtures of the same single component MOFs. Several...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2019-05, Vol.55 (37), p.5367-537
Hauptverfasser: Kalaj, Mark, Palomba, Joseph M, Bentz, Kyle C, Cohen, Seth M
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Sprache:eng
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Zusammenfassung:A library of 26 mixed ligand UiO-66 analogs was synthesized, characterized, and screened for catalytic degradation of the chemical warfare agent (CWA) simulant dimethyl 4-nitrophenylphosphate (DMNP). The MOFs were screened and compared to physical mixtures of the same single component MOFs. Several of the MOFs display higher catalytic activity than the parent UiO-66 and other single ligand UiO-66 analogues. A library of 26 mixed ligand UiO-66 analogs were synthesized, characterized, and screened for catalytic degradation of the chemical warfare agent (CWA) simulant dimethyl 4-nitrophenylphosphate (DMNP).
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc02252j