Dual copper- and photoredox-catalysed C(sp)-C(sp) coupling

Dual copper- and photoredox-catalysed C(sp)-C(sp) coupling

The use of copper catalysis with visible light photoredox catalysis in a cooperative fashion has recently emerged as a versatile means of developing new C-C bond forming reactions. In this work, dual copper and photoredox catalysis is exploited to effect C(sp 2 )-C(sp 3 ) cross-couplings between ary...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2019-04, Vol.55 (29), p.4238-4241
Hauptverfasser: McLean, Euan B, Gauchot, Vincent, Brunen, Sebastian, Burns, David J, Lee, Ai-Lan
Format: Artikel
Sprache:eng
Schlagworte:
Aromatic compounds
Bromides
Catalysis
Copper
Copper compounds
Couplings
NMR
Nuclear magnetic resonance
Optimization
Photoredox catalysis
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Zusammenfassung:The use of copper catalysis with visible light photoredox catalysis in a cooperative fashion has recently emerged as a versatile means of developing new C-C bond forming reactions. In this work, dual copper and photoredox catalysis is exploited to effect C(sp 2 )-C(sp 3 ) cross-couplings between aryl boronic acids and benzyl bromides. The use of copper catalysis with visible light photoredox catalysis in a cooperative fashion has recently emerged as a versatile means of developing new C-C bond forming reactions. In this work, dual copper and photoredox catalysis is exploited to effect C(sp 2 )-C(sp 3 ) cross-couplings between aryl boronic acids and benzyl bromides.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc01718f