Cobalt-doped hematite thin films for electrocatalytic water oxidation in highly acidic media

Earth-abundant cobalt-doped hematite thin-film electrocatalysts were explored for acidic water oxidation. The strategically doped hematite produced a stable geometric current density of 10 mA cm −2 for up to 50 h at pH 0.3, as a result of Co-enhanced intrinsic catalytic activity and charge transport...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2019, Vol.55 (34), p.517-52
Hauptverfasser: Kwong, Wai Ling, Lee, Cheng Choo, Shchukarev, Andrey, Messinger, Johannes
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Sprache:eng
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Zusammenfassung:Earth-abundant cobalt-doped hematite thin-film electrocatalysts were explored for acidic water oxidation. The strategically doped hematite produced a stable geometric current density of 10 mA cm −2 for up to 50 h at pH 0.3, as a result of Co-enhanced intrinsic catalytic activity and charge transport properties across the film matrix. Low-concentration cobalt doping improves the intrinsic activity and charge transport of hematite thin-film electrocatalyst for high-performance acidic water oxidation.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c9cc01369e