Exogenous-oxidant-free electrochemical oxidative C-H phosphonylation with hydrogen evolution

Exogenous-oxidant-free electrochemical oxidative C-H phosphonylation with hydrogen evolution

We herein report a versatile and environmentally friendly electrochemical oxidative C-H phosphonylation protocol. This protocol features a broad substrate scope; not only C(sp 2 )-H phosphonylation, but also C(sp 3 )-H phosphonylation is tolerated well under exogenous-oxidant-free and metal catalyst...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2019-04, Vol.55 (29), p.423-4233
Hauptverfasser: Yuan, Yong, Qiao, Jin, Cao, Yangmin, Tang, Jingmei, Wang, Mengqin, Ke, Guojuan, Lu, Yichen, Liu, Xue, Lei, Aiwen
Format: Artikel
Sprache:eng
Schlagworte:
Electrochemical oxidation
Hydrogen evolution
Substrates
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Zusammenfassung:We herein report a versatile and environmentally friendly electrochemical oxidative C-H phosphonylation protocol. This protocol features a broad substrate scope; not only C(sp 2 )-H phosphonylation, but also C(sp 3 )-H phosphonylation is tolerated well under exogenous-oxidant-free and metal catalyst-free electrochemical oxidation conditions. We herein report a versatile and environmentally friendly electrochemical oxidative C-H phosphonylation protocol.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc00975b