Post-synthetic fluorination of Scholl-coupled microporous polymers for increased CO2 uptake and selectivityElectronic supplementary information (ESI) available. See DOI: 10.1039/c8ta09359h

We report a facile, one-step post-synthetic fluorination method to increase the CO 2 capacity and CO 2 /N 2 selectivity of porous organic Scholl-coupled polymers. All of the fluorinated polymers that we synthesised showed increases in CO 2 /N 2 IAST selectivity and CO 2 isosteric heat; almost all materials also showed an increase in absolute CO 2 uptake. Our best-performing material (SC-TPB F) demonstrated a CO 2 capacity and CO 2 /N 2 selectivity of 3.0 mmol g −1 and 26 : 1, respectively, at 298 K-much higher than the corresponding non-fluorinated polymer, SC-TPB. This methodology might also be applicable to other polymer classes, such as polymers of intrinsic microporosity, thus providing a more general route to improvements in CO 2 capacity and selectivity. We report a facile, one-step post-synthetic fluorination method to increase the CO 2 capacity and CO 2 /N 2 selectivity of porous organic Scholl-coupled polymers.