Carbon dioxide capture in the presence of water by an amine-based crosslinked porous polymerElectronic supplementary information (ESI) available: Full synthesis and characterization details for KFUPM-1, including FT-IR and NMR spectra, gas adsorption measurements, water adsorption isotherms, and breakthrough experimental details. See DOI: 10.1039/c8ta00012c

An amine-functionalized, crosslinked porous polymer is synthesized by linking 1,4-benzenediamine and pyrrole with p -formaldehyde in the presence of hydrochloric acid catalyst. The resulting polymer was structurally characterized and proven permanently porous with a surface area of 305 m 2 g −1 . The high concentration of amines (-NH- and -NH 2 ) within the backbone of the polymer result in exceptional selectivity (141) for CO 2 over N 2 and dynamic capacity (15.1 cm 3 g −1 ) in the presence of water (20 : 80 v/v CO 2 : N 2 , 91% relative humidity, 1 bar, and 298 K). The performance of this polymer is maintained over 45 cycles without loss of selectivity, capacity, nor recyclability at room temperature; making it stand out among all porous organic materials used for carbon capture. A new cross-linked porous polymer was synthesized and its performance in the capture of carbon dioxide from a ternary gas mixture was demonstrated, and properties retained for over 45 cycles. This report represents one of the top performing porous organic materials for carbon capture.