Electrochemical Hofmann rearrangement mediated by NaBr: practical access to bioactive carbamatesElectronic supplementary information (ESI) available. See DOI: 10.1039/c8ob01059e
An electrochemical Hofmann rearrangement is reported. With the mediation of NaBr, highly corrosive and toxic halogens are avoided. Moreover, this efficient and green approach is well compatible with a broad range of amides, including several commercial medicine derivatives, and provides direct acces...
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