Two-dimensional arrays self-assembled via interference of concentration modulation waves in drying solutionsElectronic supplementary information (ESI) available. See DOI: 10.1039/c8mh01264d

The self-assembly of patterned nanostructures in solution-processed thin films with multiphase block-copolymers is successful. Generation of small and well-defined regular structures directly from single-phase polymer films is challenging. Here, a 2-dimensional (2D) patterned array of single-phase polymers was self-assembled by a solution process. One-dimensional spinodal precipitation with a characteristic wavelength was achieved along a pinned contact line of the drying solution to form a one-dimensional periodic structure (1DPS) via geometry and concentration confinement. The latter was uncovered from the liquid by sequential depinning and repinning of the contact line. A new 1DPS with an inherited phase re-emerged and triggered depinning and repinning. The process was self-repeated and a 2D array was formed with a tuneable lattice type and parameters, which was governed by the interference of two concentration-modulated waves. Self-assembly of patterned nanostructures in solution-processed thin films with single phase polymers is successful.