An intrinsically stretchable humidity sensor based on anti-drying, self-healing and transparent organohydrogelsElectronic supplementary information (ESI) available. See DOI: 10.1039/c8mh01160e

Stretchability and self-healing ability are essential attributes of modern electronic sensors for wearable applications. Herein, intrinsically ultrastretchable, self-healing and transparent humidity sensors composed of ionic κ-carrageenan/polyacrylamide (PAM) double network (DN) organohydrogels are fabricated via a facile solvent-exchange strategy. Hygroscopic ethylene glycol (EG) and glycerol (Gly) are introduced in the organohydrogels to promote both anti-drying and humidity sensing capabilities. The organohydrogel sensors display unprecedented stretchability (1225% strain) and excellent sensing performance, including fast response (0.27 s) and recovery time (0.3 s), wide relative humidity (RH) detection range (4-90%), stability and linearity. The conductance of Gly-DN sensors increases more than 543 times with increasing RH from 4% to 90%. With sufficient sensitivity, the humidity sensors can monitor human respiration with stable and repeatable output. The enhanced sensitivity and moisture-holding ability are attributed to the ready formation of hydrogen bonds between water molecules and enormous hydrophilic groups, including -OH, SO 3 − and -NH 2 , in the elaborate polymer networks and binary solvent. The hindering effect of polymer chains on the transport of conductive ions plays a key role in producing a transducing signal, which is proposed as the mechanism of the novel sensors. A facile solvent-exchange strategy is devised to fabricate anti-drying, self-healing and transparent organohydrogels for stretchable humidity sensing applications.