Magnetic investigations over reversibly switched chiral (phthalocyaninato)(porphyrinato) dysprosium double-decker compounds

Reversibly switched reduced protonated and neutral unprotonated forms of chiral mixed (phthalocyaninato)(porphyrinato) double-decker compounds were achieved, and comparative investigation over their magnetic properties firstly discovered that the introduction of f-radical interaction has a negative impact on enhancing the performance of SMMs. The present work represents one example of reversibly tuning the molecular magnetic properties of Ln-based compounds and elucidates an abnormal f-radical effect.