Catalytic removal of 1,2-dichloroethane over LaSrMnCoO6/H-ZSM-5 composite: insights into synergistic effect and pollutant-destruction mechanismElectronic supplementary information (ESI) available: XRD, physicochemical properties and catalytic performance of LaxSr2−xMnCoO6 materials. By-products distribution of 0.1LSMC/Z sample. See DOI: 10.1039/c8cy00950c

La x Sr 2− x MnCoO 6 materials with different Sr contents were prepared by a coprecipitation method, with LaSrMnCoO 6 found to be the best catalyst for 1,2-dichloroethane (DCE) destruction ( T 90 = 509 °C). As such, a series of LaSrMnCoO 6 /H-ZSM-5 composite materials were rationally synthesized to further improve the catalytic activity of LaSrMnCoO 6 . As expected, the introduction of H-ZSM-5 could remarkably enlarge the surface area, increase the number of Lewis acid sites, and enhance the mobility of the surface adsorbed oxygen species, which consequently improved the catalytic activity of LaSrMnCoO 6 . Among all the composite materials, 10 wt% LaSrMnCoO 6 /H-ZSM-5 possessed the highest catalytic activity, with 90% of 1,2-DCE destructed at 337 °C, which is a temperature reduction of more than 70 °C and 170 °C compared with that of H-ZSM-5 ( T 90 = 411 °C) and LaSrMnCoO 6 ( T 90 = 509 °C), respectively. Online product analysis revealed that CO 2 , CO, HCl, and Cl 2 were the primary products in the oxidation of 1,2-DCE, while several unfavorable reaction by-products, such as vinyl chloride, 1,1,2-trichloroethane, trichloroethylene, perchloroethylene, and acetaldehyde, were also formed via dechlorination and dehydrochlorination processes. Based on the above results, the reaction path and mechanism of 1,2-DCE decomposition are proposed. The synergy between LaSrMnCoO 6 and H-ZSM-5 in the catalytic destruction of 1,2-dichloroethane based on the dechlorination and dehydrochlorination processes.