Iridium-catalyzed 1,5-(aryl)aminomethylation of 1,3-enynes by alkenyl-to-allyl 1,4-iridium(i) migrationElectronic supplementary information (ESI) available: Experimental procedures, full spectroscopic data for new compounds. See DOI: 10.1039/c8cc09238a

A novel multicomponent coupling reaction involving the iridium-catalyzed 1,5-difunctionalization of 1,3-enynes with arylboronic acids and triazinanes is described. A key step in this 1,5-(aryl)aminomethylation reaction is the alkenyl-to-allyl 1,4-iridium( i ) migration. A novel multicomponent coupli...

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Hauptverfasser: Ruscoe, Rebecca E, Callingham, Michael, Baker, Joshua A, Korkis, Stamatis E, Lam, Hon Wai
Format: Artikel
Sprache:eng
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Zusammenfassung:A novel multicomponent coupling reaction involving the iridium-catalyzed 1,5-difunctionalization of 1,3-enynes with arylboronic acids and triazinanes is described. A key step in this 1,5-(aryl)aminomethylation reaction is the alkenyl-to-allyl 1,4-iridium( i ) migration. A novel multicomponent coupling reaction involving the iridium-catalyzed 1,5-difunctionalization of 1,3-enynes with arylboronic acids and triazinanes is described.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc09238a