Iridium-catalyzed 1,5-(aryl)aminomethylation of 1,3-enynes by alkenyl-to-allyl 1,4-iridium(i) migrationElectronic supplementary information (ESI) available: Experimental procedures, full spectroscopic data for new compounds. See DOI: 10.1039/c8cc09238a
A novel multicomponent coupling reaction involving the iridium-catalyzed 1,5-difunctionalization of 1,3-enynes with arylboronic acids and triazinanes is described. A key step in this 1,5-(aryl)aminomethylation reaction is the alkenyl-to-allyl 1,4-iridium( i ) migration. A novel multicomponent coupli...
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | A novel multicomponent coupling reaction involving the iridium-catalyzed 1,5-difunctionalization of 1,3-enynes with arylboronic acids and triazinanes is described. A key step in this 1,5-(aryl)aminomethylation reaction is the alkenyl-to-allyl 1,4-iridium(
i
) migration.
A novel multicomponent coupling reaction involving the iridium-catalyzed 1,5-difunctionalization of 1,3-enynes with arylboronic acids and triazinanes is described. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c8cc09238a |