Nickel-catalyzed intermolecular carboiodination of alkynes with aryl iodides

Nickel-catalyzed intermolecular carboiodination of alkynes with aryl iodides

Nickel-catalyzed intermolecular carboiodination of alkynes with aryl iodides to form highly substituted and functionalized alkenyl iodides has been developed. The reaction involves radical-mediated formal alkyne insertion into the carbon-nickel bond and carbon-iodine reductive elimination facilitate...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018-11, Vol.54 (9), p.1275-12753
Hauptverfasser: Takahashi, Toshifumi, Kuroda, Daiki, Kuwano, Toru, Yoshida, Yuji, Kurahashi, Takuya, Matsubara, Seijiro
Format: Artikel
Sprache:eng
Schlagworte:
Alkynes
Aromatic compounds
Carbon
Crystallography
Iodides
Iodine
Nickel
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Zusammenfassung:Nickel-catalyzed intermolecular carboiodination of alkynes with aryl iodides to form highly substituted and functionalized alkenyl iodides has been developed. The reaction involves radical-mediated formal alkyne insertion into the carbon-nickel bond and carbon-iodine reductive elimination facilitated by Ni( iii ) species. Odd-valent nickel-catalyzed intermolecular carboiodination of alkynes with aryl iodides to form highly substituted and functionalized alkenyl iodides has been developed.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc07560c