One-step construction of molecular complexity by tert-butyl nitrite (TBN)-initiated cascade α,β-sp3 C-H bond difunctionalization and C-N bond cleavageElectronic supplementary information (ESI) available: Experimental details and spectroscopic data. CCDC 1855990. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8cc06946h

One-step construction of molecular complexity by tert-butyl nitrite (TBN)-initiated cascade α,β-sp3 C-H bond difunctionalization and C-N bond cleavageElectronic supplementary information (ESI) available: Experimental details and spectroscopic data. CCDC 1855990. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8cc06946h

TBN-initiated cascade multifunctionalization of inert C-H and C-N bonds in N -arylazacycles has been realized under transition-metal free conditions, in which the synthetically useful oxime, N-NO and aldehyde functional groups were constructed in only one synthetic step. TBN initiated α,β-sp 3 C-H b...

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Hauptverfasser: He, Kaixuan, Li, Pengfei, Zhang, Shuwei, Chen, Qian, Ji, Honghe, Yuan, Yu, Jia, Xiaodong
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creator He, Kaixuan
Li, Pengfei
Zhang, Shuwei
Chen, Qian
Ji, Honghe
Yuan, Yu
Jia, Xiaodong
description TBN-initiated cascade multifunctionalization of inert C-H and C-N bonds in N -arylazacycles has been realized under transition-metal free conditions, in which the synthetically useful oxime, N-NO and aldehyde functional groups were constructed in only one synthetic step. TBN initiated α,β-sp 3 C-H bond difunctionalization and C-N bond cleavage have been realized.
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title One-step construction of molecular complexity by tert-butyl nitrite (TBN)-initiated cascade α,β-sp3 C-H bond difunctionalization and C-N bond cleavageElectronic supplementary information (ESI) available: Experimental details and spectroscopic data. CCDC 1855990. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8cc06946h
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