Inflating face-capped PdL coordination cages

Inflating face-capped PdL coordination cages

Tritopic metalloligands were used to form two Pd 6 L 8 -type coordination cages. With molecular weights of more than 15 kDa and Pd Pd distances of up to 4.2 nm, these complexes are among the largest palladium cages described to date. Using easy-to-access metalloligands, we were able to prepare Pd 6...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018-08, Vol.54 (68), p.9529-9532
Hauptverfasser: Jansze, Suzanne M, Ortiz, Daniel, Fadaei Tirani, Farzaneh, Scopelliti, Rosario, Menin, Laure, Severin, Kay
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Zusammenfassung:Tritopic metalloligands were used to form two Pd 6 L 8 -type coordination cages. With molecular weights of more than 15 kDa and Pd Pd distances of up to 4.2 nm, these complexes are among the largest palladium cages described to date. Using easy-to-access metalloligands, we were able to prepare Pd 6 L 8 -type coordination cages of unprecedented size.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc04870c