Highly enantioselective Friedel-Crafts alkylation of ,-dialkylanilines with -β-nitrostyrene catalyzed by a homochiral metal-organic framework
The first enantioselective Friedel-Crafts alkylation of N , N -dialkylanilines with trans -β-nitrostyrene catalyzed by a homochiral metal-organic framework constructed from ( R )-2,2′-dihydroxy-1,1′-binaphthyl-6,6′-dicarboxylic acid has been developed. The reaction proceeded in high yields (∼96%) wi...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2018-06, Vol.54 (49), p.6328-6331 |
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| container_issue | 49 |
| container_start_page | 6328 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 54 |
| creator | Tanaka, Koichi Sakuragi, Kenji Ozaki, Hiroto Takada, Yoshiki |
| description | The first enantioselective Friedel-Crafts alkylation of
N
,
N
-dialkylanilines with
trans
-β-nitrostyrene catalyzed by a homochiral metal-organic framework constructed from (
R
)-2,2′-dihydroxy-1,1′-binaphthyl-6,6′-dicarboxylic acid has been developed. The reaction proceeded in high yields (∼96%) with excellent enantioselectivities (∼98% ee).
The first enantioselective Friedel-Crafts alkylation of
N
,
N
-dialkylanilines with
trans
-β-nitrostyrene catalyzed by a homochiral MOF afforded the addition products in high yields (∼96%) with excellent ee (∼98%). |
| doi_str_mv | 10.1039/c8cc03447h |
| format | Article |
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N
,
N
-dialkylanilines with
trans
-β-nitrostyrene catalyzed by a homochiral metal-organic framework constructed from (
R
)-2,2′-dihydroxy-1,1′-binaphthyl-6,6′-dicarboxylic acid has been developed. The reaction proceeded in high yields (∼96%) with excellent enantioselectivities (∼98% ee).
The first enantioselective Friedel-Crafts alkylation of
N
,
N
-dialkylanilines with
trans
-β-nitrostyrene catalyzed by a homochiral MOF afforded the addition products in high yields (∼96%) with excellent ee (∼98%).</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c8cc03447h</identifier><ispartof>Chemical communications (Cambridge, England), 2018-06, Vol.54 (49), p.6328-6331</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Tanaka, Koichi</creatorcontrib><creatorcontrib>Sakuragi, Kenji</creatorcontrib><creatorcontrib>Ozaki, Hiroto</creatorcontrib><creatorcontrib>Takada, Yoshiki</creatorcontrib><title>Highly enantioselective Friedel-Crafts alkylation of ,-dialkylanilines with -β-nitrostyrene catalyzed by a homochiral metal-organic framework</title><title>Chemical communications (Cambridge, England)</title><description>The first enantioselective Friedel-Crafts alkylation of
N
,
N
-dialkylanilines with
trans
-β-nitrostyrene catalyzed by a homochiral metal-organic framework constructed from (
R
)-2,2′-dihydroxy-1,1′-binaphthyl-6,6′-dicarboxylic acid has been developed. The reaction proceeded in high yields (∼96%) with excellent enantioselectivities (∼98% ee).
The first enantioselective Friedel-Crafts alkylation of
N
,
N
-dialkylanilines with
trans
-β-nitrostyrene catalyzed by a homochiral MOF afforded the addition products in high yields (∼96%) with excellent ee (∼98%).</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFT0tOwzAUtBBIlM-GPdI7AIZETmi6rqh6ABbdVQ_npX7UsdGzRWUOwWE4CGciCCSWzGZGM6ORRqmrurqtK7O4s521lWmauTtSs9rcN7ptus3xt24Xem6a9lSdpfRcTajbbqbe17xzvgAFDJljIk828yvBSph68nopOOQE6PfF49QIEAe40T3_OIE9B0pw4OxAf37owFliykUoEFjM6Msb9fBUAMHFMVrHgh5GmhIdZTctWBgERzpE2V-okwF9ostfPlfXq4fH5VpLstsX4RGlbP9Omv_yL0LmWeo</recordid><startdate>20180614</startdate><enddate>20180614</enddate><creator>Tanaka, Koichi</creator><creator>Sakuragi, Kenji</creator><creator>Ozaki, Hiroto</creator><creator>Takada, Yoshiki</creator><scope/></search><sort><creationdate>20180614</creationdate><title>Highly enantioselective Friedel-Crafts alkylation of ,-dialkylanilines with -β-nitrostyrene catalyzed by a homochiral metal-organic framework</title><author>Tanaka, Koichi ; Sakuragi, Kenji ; Ozaki, Hiroto ; Takada, Yoshiki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c8cc03447h3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2018</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Tanaka, Koichi</creatorcontrib><creatorcontrib>Sakuragi, Kenji</creatorcontrib><creatorcontrib>Ozaki, Hiroto</creatorcontrib><creatorcontrib>Takada, Yoshiki</creatorcontrib><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tanaka, Koichi</au><au>Sakuragi, Kenji</au><au>Ozaki, Hiroto</au><au>Takada, Yoshiki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly enantioselective Friedel-Crafts alkylation of ,-dialkylanilines with -β-nitrostyrene catalyzed by a homochiral metal-organic framework</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2018-06-14</date><risdate>2018</risdate><volume>54</volume><issue>49</issue><spage>6328</spage><epage>6331</epage><pages>6328-6331</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>The first enantioselective Friedel-Crafts alkylation of
N
,
N
-dialkylanilines with
trans
-β-nitrostyrene catalyzed by a homochiral metal-organic framework constructed from (
R
)-2,2′-dihydroxy-1,1′-binaphthyl-6,6′-dicarboxylic acid has been developed. The reaction proceeded in high yields (∼96%) with excellent enantioselectivities (∼98% ee).
The first enantioselective Friedel-Crafts alkylation of
N
,
N
-dialkylanilines with
trans
-β-nitrostyrene catalyzed by a homochiral MOF afforded the addition products in high yields (∼96%) with excellent ee (∼98%).</abstract><doi>10.1039/c8cc03447h</doi><tpages>4</tpages></addata></record> |
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| ispartof | Chemical communications (Cambridge, England), 2018-06, Vol.54 (49), p.6328-6331 |
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| recordid | cdi_rsc_primary_c8cc03447h |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Highly enantioselective Friedel-Crafts alkylation of ,-dialkylanilines with -β-nitrostyrene catalyzed by a homochiral metal-organic framework |
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